Water has a rotation axis that bisects the H-O-H angle. Rotation of 180° about this axis gives a molecule indistinguishable from the original. In this example, n=2 (180 = 360/2). Thus, water has a two fold axis of rotation, and the Schoenflies symbol is C2.
Chloroform has a rotation axis coincident with the C-H bond. Rotation of 120° about the C-H bond gives a molecule indistinguishable from the original. In this example, n=3 (120 = 360/3). Thus, chloroform has a three fold axis of rotation, and the Schoenflies symbol is C3.
Square planer PtCl42- has four C2 rotation axis, two coincident with Pt-Cl bonds, and two that bisect Cl-Pt-Cl angles. More importantly, there is also a C4 axis perpendicular to the plane of the five atoms. Rotation of 90° about this axis gives a molecule indistinguishable from the original. In this example, n=4 (90 = 360/4). Thus, PtCl42- has a four fold axis of rotation.